MersV1, Main, Exploration, bibRecord, 002775

Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]

Identifieur interne : 002775 ( Main/Exploration ); précédent : 002774; suivant : 002776

Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]

Auteurs : Karyn M. Blake [États-Unis] ; Robert L. Laduca [États-Unis]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2009.

RBID : PMC:2977128

Abstract

In the title compound, {[CdCl₂(C₁₆H₂₀N₄)₂]·4H₂O}_n, octahedrally coordinated Cd^II ions, situated on crystallographic inversion centres, bearing trans-disposed chloride ligands, are linked into (4,4)-grid coordination polymer layers by tethering 1,4-bis(3-pyridylmethyl)piperazine ligands. The layers are aligned parallel to the (01) crystal planes and aggregate by means of O—H⋯N, O—H⋯O and O—H⋯Cl hydrogen-bonding mechanisms imparted by cyclic water molecule tetramers.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977128

DOI: 10.1107/S1600536809027767
PubMed: 21583397
PubMed Central: 2977128

Affiliations:

États-Unis

Le document en format XML

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:<italic>N</italic>
′]dichloridocadmium(II)] tetrahydrate]</title>
<author><name sortKey="Blake, Karyn M" sort="Blake, Karyn M" uniqKey="Blake K" first="Karyn M." last="Blake">Karyn M. Blake</name>
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</nlm:aff>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<front><div type="abstract" xml:lang="en"><p>In the title compound, {[CdCl<sub>2</sub>
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N<sub>4</sub>
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, octahedrally coordinated Cd<sup>II</sup>
 ions, situated on crystallographic inversion centres, bearing <italic>trans</italic>
-disposed chloride ligands, are linked into (4,4)-grid coordination polymer layers by tethering 1,4-bis(3-pyridylmethyl)piperazine ligands. The layers are aligned parallel to the (<inline-formula><inline-graphic xlink:href="e-65-0m947-efi7.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
01) crystal planes and aggregate by means of O—H⋯N, O—H⋯O and O—H⋯Cl hydrogen-bonding mechanisms imparted by cyclic water molecule tetramers.</p>
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Serveur d'exploration MERS

Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]

Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]

Source :

Abstract

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	Serveur d'exploration MERS
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Serveur d'exploration MERS

Poly[[bis­[μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ2N:N′]dichlorido­cadmium(II)] tetra­hydrate]

Poly[[bis­[μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ2N:N′]dichlorido­cadmium(II)] tetra­hydrate]

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Abstract

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Pour générer des pages wiki

Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]

Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]